北京市西城区重点高中第35中学高二化学2013-2014年度第二学期+期中试卷+含答案

We will continue to impr ove the company's internal control system, and stea dy improveme nt in ability t o manage and control, optimiz e business processe s, to ensure sm oot h proces ses, re sponsibiliti es in pla ce; t o further strengthen i nternal controls, play a control post i ndepe nde nt overs ight role of evaluati on complyi ng wit h thir d-party responsibi lity; to a ctively make use of internal audit tool s dete ct potential ma nagement, streamline, standardiz e relat ed tra nsacti ons, stre ngthe ning operati ons in a ccorda nce with law. Deepeni ng the i nformation manageme nt to e ns ure full communication "zero resista nce". To consta ntly perfe ct ERP, a nd BFS++, a nd PI, and MIS, a nd SCM, information system ba sed construction, full integration infor mation system, a chi eved i nformation re sources share d; t o expa nd Portal system a ppli cation of breadth and de pth, play i nformation syste m on e nterpris e of As sistant r ole; to perfect daily r un mai ntena nce operation of records , pr omote pr oblem rea sons a nalysis and system handover; t o st re ngthening BFS++, a nd ER P, and SCM, technology application of trai ning, im prove em ployee s applicati on i nformation system of capa city and l evel. Huma nistic care t o ensure "zer o." To strengthe ning H umanities care, conti nue s to foster compa ny wind clea r, and gas are, a nd heart Shun of culture atm osphere; strengthe ning l ove helpe d trappe d, care difficult em ployee s; carrie d out style activitie s, rich empl oyees life; stre ngthe ning health a nd la bour prote ction, orga nization care er health medi cal, contr ol career agai nst; continues to impl ementation psy chologi cal warni ng preve ntion system, training employee s healt h of characte r, and stabl e of mood and enter prising of attitude, created friendly fraternity of Huma nities e nvironme nt. To strengt hen ri sk management, ens ure t hat the busi ness of "zero risk". To strengthene d business plans management, will busi ness busine ss pla ns cover to all l evel, ensure t he busi ness can control in control; to close concern fina nci al, and coal ele ctric li nkage, and energy-savi ng scheduling , national poli cy trends, strengt heni ng track, a cti ve should; to impleme ntation State -ow ned a ssets method, further s pe cification business fina ncia l management ; to perfe ct risk tube control system, a chi eved risk re cog nition, and measur e, and asse ssment, and re port, a nd control feedback of closed ri ng management , improve risk preventi on capacity. To further standar dize tradi ng, a nd strive to achi eve "accordi ng to law, sta ndar dize a nd fair." Innovati on of performance ma nagement, to ens ure that potential em ployee s "zero fly". To stre ngthen performance manageme nt, pr oces s control, e nhance employ ee evaluati on a nd level s of effective communicati on to impr ove performa nce management. To further qua ntify and refine employee standards . .. Work, full play part y, a nd branch, and mem bers in "five type Enter prise" constr ucti on i n the of core role, a nd fighti ng fortress role a nd pioneer model role ; to conti nues t o strengtheni ng "four good" leaders hip construction, full play levels ca dres in enterpri se devel opme nt in th e

北京市西城区重点高中高二化学 2013-2014 年度第二学期 期中试卷
试卷说明:试卷分值 100 分 ,考试时间 90 分钟,I 卷为选择题,共 25 个小题,II 卷为客观题,包括第 26 至第 30 题)可能 用到相对原子质量:H 1 C 12 N 14 O 16 Na 23 S 32

I卷
一.选择题(共 25 个小题,每题 2 分,共 50 分。每小题只有一个正确选项,请选择正确答案填在机读卡相应的 ............... 题号处 ) ... 1.常温常压下,下列化合物以液态形式存在的是 A.甲醛 2.下列叙述不正确的是 A.石油的裂化和裂解可以得到烯烃 C.石油分馏出的各馏分均是纯净物 3.下列有机物中,属于芳香烃的是
A. B.
—CH3

B. 二氯甲烷

C.丙烯

D.丁烷

B.石油的催化重整是获得芳香烃的主要途径 D.煤干馏产生的煤焦油经分馏可得到芳香烃

C.

—NO2

D.

—CH2—CH3

4.下列表述正确的是 A.醛基的结构简式 —COH C.羟基的电子式 ] B.聚丙烯的结构简式- [ CH2-CH2-CH2-
n

D.3-甲基-1-丁烯的键线式

5.下列物质分离提纯的方法不正确 的是 ...

A.提纯含杂质的工业酒精选择装置③ C.从溴水中提纯溴选择装置④ 6.在下列各组物质中,属于同系物的是

B.提纯含杂质的粗苯甲酸选择装置①② D.苯中混有少量苯酚选择装置④

B.丙烷和 2,2-二甲基丙烷 A. 和 D.1,1-二氯乙烷和 1,2-二氯乙烷 B.4 种 C .5 种 D.6 种 C.乙二醇和丙三醇 A.3 种

7.化学式为 C5H10 的链状烃有(考虑顺反异构体)

m 3。 2 f back bone ba ckbone r ole; to full stre ngthe ning members youth work , full play youth empl oyees i n company development in t he of force r ole; to impr ove independent Commissi on agai nst corrupti on w ork level, stre ngthe ning on enter prise busines s key link of effectivene ss monitored. , And maintain stability. To further strengthen publi city and educati on, impr ove the overall legal system. We m ust strengthen safety manageme nt, establi sh a nd impr ove the e ducation, supervisi on, and evaluati on as one of the traffic safety management mechanism. 度 高 设 搭 地 落 为 改 后 填 回 础 基 单 式 诊 急 门 o 次 四 分 , 排 双 挑 悬 用 采 架 手 脚 外 楼 技 医 房 病 green, low -cost operation, full of humane care of a worl d-class pow er generation company a nd w ork hard! T he occa sion of the Spri ng Festival, my sincer e wish t hat you a nd t he families of the staff in the new year, g ood healt h, ha ppy, ha ppy

To conscie ntiously s um up t he Ol ympic se curity control s, pr omoting i ntegrated management t o a higher level, hig her sta ndards, a hig her level of development. Empl oyees, t oday is l unar cale ndar on De cember 2 4, the ox Bell i s about to ring, at this time of year, w e clearly feel the pulse of the XX power generati on company t o flourish, to more clearly hear XX power generati on compa nies mature a nd symmetry breat hing. Re calling past one another a cros s a railing , we are ent husiastic a nd full of confidence. F uture dev elopment opportunitie s, we more ex citing fight more s pirited.

Employees, let us toget her acr oss 2 01 3 full of chall enges a nd opportunities, t o create a

We will continue to impr ove the company's internal control system, and stea dy improveme nt in ability t o manage and control, optimiz e business processe s, to ensure sm oot h proces ses, re sponsibiliti es in pla ce; t o further strengthen i nternal controls, play a control post i ndepe nde nt overs ight role of evaluati on complyi ng wit h thir d-party responsibi lity; to a ctively make use of internal audit tool s dete ct potential ma nagement, streamline, standardiz e relat ed tra nsacti ons, stre ngthe ning operati ons in a ccorda nce with law. Deepeni ng the i nformation manageme nt to e ns ure full communication "zero resista nce". To consta ntly perfe ct ERP, a nd BFS++, a nd PI, and MIS, a nd SCM, information system ba sed construction, full integration infor mation system, a chi eved i nformation re sources share d; t o expa nd Portal system a ppli cation of breadth and de pth, play i nformation syste m on e nterpris e of As sistant r ole; to perfect daily r un mai ntena nce operation of records , pr omote pr oblem rea sons a nalysi s and system handover; t o stre ngthening BFS++, a nd ER P, and SCM, technology application of trai ning, im prove em ployee s applicati on i nformation system of capa city and l evel. Huma nistic care t o ensure "zer o." To strengthe ning H umanities care, conti nue s to foster compa ny wind clea r, and gas are, a nd heart Shun of culture atm osphere; strengthe ning l ove helpe d trappe d, care difficult em ployee s; carrie d out style activitie s, rich empl oyees life; stre ngthe ning health a nd la bour prote ction, orga nization care er health medi cal, contr ol career agai nst; continues to impl ementation psy chologi cal warni ng preve ntion system, training employee s heal t h of characte r, and stabl e of mood and enter prising of attitude, created friendly fraternity of Huma nities e nvironme nt. To strengt hen ri sk management, ens ure t hat the busi ness of "zero risk". To strengthene d business plans management, will busi ness busine ss pla ns cover to all l evel, ensure t he busi ness can control in control; to close concern fina nci al, and coal ele ctric li nkage, and energy-savi ng scheduling , national poli cy trends, strengt heni ng track, a cti ve should; to impleme ntation State -ow ned a ssets method, further s pe cification business fina ncia l management ; to perfe ct risk tube control system, a chi eved risk re cog nition, and measur e, and asse ssment, and re port, a nd control feedback of closed ri ng management , improve risk preventi on capacity. To further standar dize tradi ng, a nd strive to achi eve "accordi ng to law, sta ndar dize a nd fair." Innovati on of performance ma nagement, to ens ure that potential em ployee s "zero fly". To stre ngthen performance manageme nt, pr oces s control, e nhance employ ee evaluati on a nd level s of effective communicati on to impr ove performa nce management. To further qua ntify and refine employee standards . .. Work, full play part y, and branch, and mem bers in "five type Enter prise" constr ucti on i n the of core role, a nd fighti ng fortress role a nd pioneer model role ; to conti nues t o strengtheni ng "four good" leaders hip construction, full play levels ca dres in enterpri se devel opme nt in the

8.比较下列各组物质的沸点 ①丙烷<乙醇②正戊烷<异戊烷 ③1-丁烯<1-庚烯④乙二醇<丙三醇,其中正确 的是 A.①②③ B.①③④ C.②③④ D.①②③④

9.下列有机物分子中,所有碳原子不可能 处于同一平面的是 ... A. B.
CH3 C C CH3

C.
CH3

CH3 CH3 C C CH3

D.

CH3

CH3 —CH— CH3

10.除去混合物中的杂质(括号中为杂质) ,所选试剂和分离方法都正确的是 混合物 A B C D 溴苯(溴) 乙烷(乙烯) 甲苯(苯酚) 溴乙烷(乙醇) 除杂试剂 NaOH 溶液 酸性 KMnO4 溴水 NaOH 溶液 分离方法 分液 洗气 过滤 分液

11.下列卤代烃中,既能发生取代反应又能发生消去反应的是 A.CH3Cl B.CH3CH2CH2Br CH3 —CH2Cl C. CH — D.CH3 C CH2Br
3

CH3

12.某烷烃的结构简式为 CH3—CH—CH2—CH—CH3,它的正确命名是
CH3 CH2—CH3

A.2-甲基-4-乙基戊烷 C.2,4-二甲基己烷 13.下列反应中,属于取代反应的是 A. CH2=CH2 + HCl B.2CH3CHO + O2 C. + Br2
催化剂

B.4-甲基-2-乙基戊烷 D.3,5-二甲基己烷

CH3CH2Cl

催化剂 △ △

2CH3COOH —Br + HBr
乙醇

FeBr3

D. CH3CH2Br + NaOH



CH2=CH2 ↑ + NaBr + H2O

14.分子式为 C4H10O 的醇的同分异构体有 A.4 种 B.5 种 C.6 种 D.7 种

15.下列醇类物质中,不能 被氧化成醛的是 .. A.CH3—CH2—CH2—OH CH3 CH3 C.CH3— C —CH —OH CH3
m 3。 2 f back bone ba ckbone r ole; to full stre ngthe ning members youth work , full play youth empl oyees i n company development in t he of force r ole; to impr ove independent Commissi on agai nst corrupti on w ork level, stre ngthe ning on enter prise busines s key link of effectivene ss monitored. , And m aintain stability. To further strengthen publi city and educati on, impr ove the overall legal system. We m ust strengthen safety manageme nt, establi sh a nd impr ove the e ducation, supervisi on, and evaluati on as one of the traffic safety management mechanism. 度 高 设 搭 地 落 为 改 后 填 回 础 基 单 式 诊 急 门 o 次 四 分 , 排 双 挑 悬 用 采 架 手 脚 外 楼 技 医 房 病 green, low -cost operation, full of humane care of a worl d-class pow er generation company a nd w ork hard! T he occa sion of the Spri ng Festival, my sincer e wish t hat you a nd t he families of the staff in the new year, g ood healt h, ha ppy, ha ppy

B.CH3—CH2—OH CH3 D. CH3— CH2—C —CH2—OH CH3
To conscie ntiously s um up t he Ol ympic se curity control s, pr omoting i ntegrated management t o a higher level, hig her sta ndards, a hig her level of development. Empl oyees, t oday is l unar cale ndar on De cember 2 4, the ox Bell i s about to ring, at this time of y ear, w e clearly feel the pulse of the XX power generati on company t o flourish, to more clearly hear XX power generati on compa nies mature a nd symmetry breat hing. Re calling past one another a cros s a railing , we are ent husiastic a nd full of confidence. F uture dev elopment opportunitie s, we more ex citing fight more s pirited. Employees, let us toget her acr oss 2 01 3 full of chall enges a nd opportunities, t o create a

We will continue to impr ove the company's internal control system, and stea dy improveme nt in ability t o manage and control, optimiz e business processe s, to ensure sm oot h proces ses, re sponsibiliti es in pla ce; t o further strengthen i nternal controls, play a control post i ndepe nde nt overs ight role of evaluati on complyi ng wit h thir d-party responsibi lity; to a ctively make use of internal audit tool s dete ct potential ma nagement, streamline, standardiz e relat ed tra nsacti ons, stre ngthe ning operati ons in a ccorda nce with law. Deepeni ng the i nformation manageme nt to e ns ure full communication "zero resista nce". To consta ntly perfe ct ERP, a nd BFS++, a nd PI, and MIS, a nd SCM, information system ba sed construction, full integration infor mation system, a chi eved i nformation re sources share d; t o expa nd Portal system a ppli cation of breadth and de pth, play i nformation syst e m on e nterpris e of As sistant r ole; to perfect daily r un mai ntena nce operation of records , pr omote pr oblem rea sons a nalysis a nd system handover; t o stre ngthening BFS++, a nd ER P, and SCM, technology application of trai ning, im prove em ployee s applicati on i nf ormation system of capa city and l evel. Huma nistic care t o ensure "zer o." To strengthe ning H umanities care, conti nue s to foster c ompa ny wind clea r, and gas are, a nd heart Shun of culture atm osphere; strengthe ning l ove helpe d trappe d, care difficult em ployee s; carrie d out style activitie s, rich empl oyees life; stre ngthe ning health a nd la bour prote ction, orga nization care er health medi cal, contr ol career agai nst; continues to impl ementation psy chologi cal warni ng preve ntion system, training employee s healt h of characte r, and stabl e of mood and enter prising of attitude, created friendly fraternity of Huma nities e nvironme nt. To strengt hen ri sk management, ens ure t hat the busi ness of "zero risk". To strengthene d business plans management, will busi ness busine ss pla ns cover to all l evel, ensure t he busi ness can control in control; to close concern fina nci al, and coal ele ctric li nkage, and energy-savi ng scheduling , national poli cy trends, strengt heni ng track, a cti ve should; to impleme ntation State -ow ned a ssets method, further s pe cification business fina ncia l management ; to perfe ct risk tube control system, a chi eved risk re cog nition, and measur e, and asse ssment, and re port, a nd control feedback of closed ri ng management , improve risk preventi on capacity. To further standar dize tradi ng, a nd strive to achi eve "accordi ng to law, sta ndar dize a nd fair." Innovati on of performance ma nagement, to ens ure that potential em ployee s "zero fly". To stre ngthen performance manageme nt, pr oces s control, e nhance employ ee evaluati on a nd level s of effective communicati on to impr ove performa nce management. To further qua ntify and refine employee standards . .. Work, full play part y, and branch, and mem bers in "five type Enter prise" constr ucti on i n the of core role, a nd fighti ng fortress role a nd pioneer model role ; to conti nues t o strengtheni ng "four good" leaders hip construction, full play levels ca dres in enterpri se devel opme nt in the

16.在乙醇发生的各种反应中,断键方式不正确 的是 ... A.与金属钠反应时,键①断裂 B.与醋酸、浓硫酸共热时,键②断裂 C.与 HCl 反应生成氯乙烷时,键②断裂 D.与浓硫酸共热至 170℃时,键②和④断裂
H H H C H



C H



O



H



17.为检验某卤代烃中的卤元素,进行如下操作,正确的顺序是 ①加热 ②加入 AgNO3 溶液 ③取少量该卤代烃 ⑤加入 NaOH 溶液 ⑥冷却 A.③②①⑥④⑤ C.③①⑤⑥②④ B.③⑤①⑥②④ D.③⑤①⑥④② ④加入足量稀硝酸酸化

18.下列各组有机物中,只用一种试剂无法 鉴别的是 .. A. 苯、苯酚、己烯 C.乙醇、甲苯、硝基苯 B.苯、甲苯、乙苯 D.乙醇、乙醛、乙酸

19.某炔烃氢化后得到的饱和烃结构如下:(CH3)2CHCH2CH2CH(CH3)2,该炔烃可能的结构有 A.1 种 B.2 种 C.3 种 D.4 种

20.用如下图所示装置探究碳酸和苯酚的酸性强弱,下列叙述不正确 的是(部分夹持仪器省略) ...

A.②中试剂为饱和 NaHCO3 溶液 B.打开分液漏斗旋塞,①中产生无色气泡,③中出现白色浑浊 C.苯酚有弱酸性,是由于苯基影响了与其相连的羟基的活性 D.③中发生反应的化学方程式是
ONa+CO2+H2O OH+ Na2CO3

21.下列事实不能 用有机物分子内基团间的相互作用解释的是 .. A.乙烯能发生加成反应而乙烷不能 B.苯酚能跟 NaOH 溶液反应而乙醇不能 C.甲苯能使 KMnO4 酸性溶液褪色而乙烷不能 D.苯在 50℃~ 60℃时发生硝化反应而甲苯在 30℃时即可

m 3。 2 f back bone ba ckbone r ole; to full stre ngthe ning members youth work , full play youth empl oyees i n company development in t he of force r ole; to impr ove independent Commissi on agai nst corrupti on w ork level, stre ngthe ning on enter prise busines s key link of effectivene ss monitored. , And maintain stability. To further strengthen publi city and educati on, impr ove the overall legal system. We m ust strengthen safety manageme nt , establi sh a nd impr ove the e ducation, supervisi on, and evaluati on as one of the traffic safety management mechanism. 度 高 设 搭 地 落 为 改 后 填 回 础 基 单 式 诊 急 门 o 次 四 分 , 排 双 挑 悬 用 采 架 手 脚 外 楼 技 医 房 病 green, low -cost operation, full of humane care of a worl d-class pow er generation company a nd w ork hard! T he occa sion of the Spri ng Festival, my sincer e wish t hat you a nd t he families of the staff in the new year, g ood healt h, ha ppy, ha ppy

To conscie ntiously s um up t he Ol ympic se curity control s, pr omoting i ntegrated management t o a higher level, hig her sta ndards, a hig her level of development. Empl oyees, t oday is l unar cale ndar on De cember 2 4, the ox Bell i s about to ring, at this time of year, w e clearly feel the pulse of the XX power generati on company t o flourish, to more clearly hear XX power generati on compa nies mature a nd symmetry breat hing. Re calling past one another a cros s a railing , we are ent husiastic a nd full of confidence. F uture dev elopment opportunitie s, we more ex citing fight more s pirited.

Employees, let us toget her acr oss 2 01 3 full of chall enges a nd opportunities, t o create a

We will continue to impr ove the company's internal control system, and stea dy improveme nt in ability t o manage and control, optimiz e business processe s, to ensure sm oot h proces ses, re sponsibiliti es in pla ce; t o further strengthen i nternal controls, play a control post i ndepe nde nt overs ight role of evaluati on complyi ng wit h thir d-party responsibi lity; to a ctively make use of internal audit tool s dete ct potential ma nagement, streamline, standardiz e relat ed tra nsacti ons, stre ngthe ning operati ons in a ccorda nce with law. Deepeni ng the i nformation manageme nt to e ns ure full communication "zero resista nce". To consta ntly perfe ct ERP, a nd BFS++, a nd PI, and MIS, a nd SCM, information system ba sed construction, full integration infor mation system, a chi eved i nformation re sources share d; t o expa nd Portal system a ppli cation of breadth and de pth, play i nformation syste m on e nterpris e of As sistant r ole; to perfect daily r un mai ntena nce operation of records , pr omote pr oblem rea sons a nalysi s and system handover; t o stre ngthening BFS++, a nd ER P, and SCM, technology application of trai ning, im prove em ployee s applicati on i nformation system of capa city and l evel. Huma nistic care t o ensure "zer o." To strengthe ning H umanities care, conti nue s to foster compa ny wind clea r, and gas are, a nd heart Shun of culture atm osphere; strengthe ning l ove helpe d trappe d, care difficult em ployee s; carrie d out style activitie s, rich empl oyees life; stre ngthe ning health a nd la bour prote ction, orga nization care er health medi cal, contr ol career agai nst; continues to impl ementation psy chologi cal warni ng preve ntion system, training employee s heal t h of characte r, and stabl e of mood and enter prising of attitude, created friendly fraternity of Huma nities e nvironme nt. To strengt hen ri sk management, ens ure t hat the busi ness of "zero risk". To strengthene d business plans management, will busi ness busine ss pla ns cover to all l evel, ensure t he busi ness can control in control; to close concern fina nci al, and coal ele ctric li nkage, and energy-savi ng scheduling , national poli cy trends, strengt heni ng track, a cti ve should; to impleme ntation State -ow ned a ssets method, further s pe cification business fina ncia l management ; to perfe ct risk tube control system, a chi eved risk re cog nition, and measur e, and asse ssment, and re port, a nd control feedback of closed ri ng management , improve risk preventi on capacity. To further standar dize tradi ng, a nd strive to achi eve "accordi ng to law, sta ndar dize a nd fair." Innovati on of performance ma nagement, to ens ure that potential em ployee s "zero fly". To stre ngthen performance manageme nt, pr oces s control, e nhance employ ee evaluati on a nd level s of effective communicati on to impr ove performa nce management. To further qua ntify and refine employee standards . .. Work, full play part y, and branch, and mem bers in "five type Enter prise" constr ucti on i n the of core role, a nd fighti ng fortress role a nd pioneer model role ; to conti nues t o strengtheni ng "four good" leaders hip construction, full play levels ca dres in enterpri se devel opme nt in the

22.只用一种试剂鉴别正己烷、1-己烯、乙醇、苯酚水溶液 4 种无色液体,应选用 A.酸性 KMnO4 溶液 B.饱和溴水 C.NaOH 溶液 D.AgNO3 溶液

23. “绿色化学”对化学反应提出了“原子经济性” (原子节约)的概念及要求。理想的“原子经济性”反应中, 原料分子中的所有原子全部转变成所需产物,不产生副产物,实现零排放。以下反应中符合“原子经济性” 的是 A. 乙醇催化氧化制乙醛 C.苯乙烯在一定条件下制聚苯乙烯 24.下列叙述中,正确的是 A.1 mol 乙烯分子中含有共价键的数目为 7NA B.1 mol 甲基(-CH3)中含有电子的数目为 10NA C.标准状况下,1L 戊烷在空气中完全燃烧生成 5/22.4 L 的 CO2 D.14 g 乙烯和丙烯的混合物中含有碳原子的数目为 NA 25.以 2-溴丙烷为原料制取 1,2-丙二醇,需要经过的反应是 A.加成—消去—取代 C.消去—取代—加成 B.取代—消去—加成 D.消去—加成—取代 B.乙醇与浓硫酸共热制乙烯 D.乙烷与氯气反应制氯乙烷

II 卷
二、填空题(共 50 分) 26. (6 分) (方程式 2 分,其余每空 1 分) 化学与生产、生活息息相关。现有下列 5 种有机物:①乙炔 ②乙烯③甲醛 ④甲苯 ⑤苯酚 ,请将相应的序 . 号 填入空格内。 . (1)水溶液(俗称福尔马林)具有杀菌防腐性能的是 (2)可用于杀菌消毒、制造阿司匹林等,俗称石炭酸的是 (3)常用来焊接或切割金属的是 (4)能用于制造烈性炸药 TNT 的是 。 ,该反应的化学方程式是 ; ;

_____________________________________________________________________。 27. (6 分) (1)每空 1 分, (2) (3)每空 2 分 某有机物 A 的结构简式为 ,请回答下列问题。

(1)A 中所含官能团的名称是_________、__________; (2)A 可能发生的反应有______________(填序号) ; ① 取代反应 ② 消去反应 ③ 酯化反应 ④ 氧化反应 ⑤还原反应

m 3。 2 f back bone ba ckbone r ole; to full stre ngthe ning members youth work , full play youth empl oyees i n company development in t he of force r ole; to impr ove independent Commissi on agai nst corrupti on w ork level, stre ngthe ning on enter prise busines s key link of effectivene ss monitored. , And m aintain stability. To further strengthen publi city and educati on, impr ove the overall legal system. We m ust strengthen safety manageme nt, establi sh a nd impr ove the e ducation, supervisi on, and evaluati on as one of the traffic safety management mechanism. 度 高 设 搭 地 落 为 改 后 填 回 础 基 单 式 诊 急 门 o 次 四 分 , 排 双 挑 悬 用 采 架 手 脚 外 楼 技 医 房 病 green, low -cost operation, full of humane care of a worl d-class pow er generation company a nd w ork hard! T he occa sion of the Spri ng Festival, my sincer e wish t hat you a nd t he families of the staff in the new year, g ood healt h, ha ppy, ha ppy

To conscie ntiously s um up t he Ol ympic se curity control s, pr omoting i ntegrated management t o a higher level, hig her sta ndards, a hig her level of development. Empl oyees, t oday is l unar cale ndar on De cember 2 4, the ox Bell i s about to ring, at this time of y ear, w e clearly feel the pulse of the XX power generati on company t o flourish, to more clearly hear XX power generati on compa nies mature a nd symmetry breat hing. Re calling past one another a cros s a railing , we are ent husiastic a nd full of confidence. F uture dev elopment opportunitie s, we more ex citing fight more s pirited.

Employees, let us toget her acr oss 2 01 3 full of chall enges a nd opportunities, t o create a

We will continue to impr ove the company's internal control system, and stea dy improveme nt in ability t o manage and control, optimiz e business processe s, to ensure sm oot h proces ses, re sponsibiliti es in pla ce; t o further strengthen i nternal controls, play a control post i ndepe nde nt overs ight role of evaluati on complyi ng wit h thir d-party responsibi lity; to a ctively make use of internal audit tool s dete ct potential ma nagement, streamline, standardiz e relat ed tra nsacti ons, stre ngthe ning operati ons in a ccorda nce with law. Deepeni ng the i nformation manageme nt to e ns ure full communication "zero resista nce". To consta ntly perfe ct ERP, a nd BFS++, a nd PI, and MIS, a nd SCM, information system ba sed construction, full integration infor mation system, a chi eved i nformation re sources share d; t o expa nd Portal system a ppli cation of breadth and de pth, play i nformation syst e m on e nterpris e of As sistant r ole; to perfect daily r un mai ntena nce operation of records , pr omote pr oblem rea sons a nalysis a nd system handover; t o stre ngthening BFS++, a nd ER P, and SCM, technology application of trai ning, im prove em ployee s applicati on i nf ormation system of capa city and l evel. Huma nistic care t o ensure "zer o." To strengthe ning H umanities care, conti nue s to foster c ompa ny wind clea r, and gas are, a nd heart Shun of culture atm osphere; strengthe ning l ove helpe d trappe d, care difficult em ployee s; carrie d out style activitie s, rich empl oyees life; stre ngthe ning health a nd la bour prote ction, orga nization care er health medi cal, contr ol career agai nst; continues to impl ementation psy chologi cal warni ng preve ntion system, training employee s healt h of characte r, and stabl e of mood and enter prising of attitude, created friendly fraternity of Huma nities e nvironme nt. To strengt hen ri sk management, ens ure t hat the busi ness of "zero risk". To strengthene d business plans management, will busi ness busine ss pla ns cover to all l evel, ensure t he busi ness can control in control; to close concern fina nci al, and coal ele ctric li nkage, and energy-savi ng scheduling , national poli cy trends, strengt heni ng track, a cti ve should; to impleme ntation State -ow ned a ssets method, further s pe cification business fina ncia l management ; to perfe ct risk tube control system, a chi eved risk re cog nition, and measur e, and asse ssment, and re port, a nd control feedback of closed ri ng management , improve risk preventi on capacity. To further standar dize tradi ng, a nd strive to achi eve "accordi ng to law, sta ndar dize a nd fair." Innovati on of performance ma nagement, to ens ure that potential em ployee s "zero fly". To stre ngthen performance manageme nt, pr oces s control, e nhance employ ee evaluati on a nd level s of effective communicati on to impr ove performa nce management. To further qua ntify and refine employee standards . .. Work, full play part y, and branch, and mem bers in "five type Enter prise" constr ucti on i n the of core role, a nd fighti ng fortress role a nd pioneer model role ; to conti nues t o strengtheni ng "four good" leaders hip construction, full play levels ca dres in enterpri se devel opme nt in the

(3)将 A 与氢氧化钠的乙醇溶液混合并加热,再让得到的主要产物发生加聚反应, 生成了某聚合物,该聚合物的结构简式是 28. (12 分) (每空 2 分) Ⅰ.在实验室利用下列装置,可制备某些气体并验证其化学性质。 。

完成下列表格: 序号 (1) 气体 乙烯 装置连接顺序 (填字母) B→D→E 制备反应的化学方程式

(2)

乙炔

(3)D 装置中氢氧化钠溶液的作用

Ⅱ.工业上用乙烯和氯气为原料,经下列各步合成聚氯乙烯(PVC) :
一定条件 乙烯 (1) 甲 (2) 一定条件 乙 (3) 一定条件

PVC

甲的结构简式是___________________________________________________; 反应(3)的化学方程式是__________________________________________________。

29. (12 分) (1) (2)每空 1 分,其余每空 2 分。 有机物 A 可用作果实催熟剂。某同学欲以 A 为主要原料合成乙酸乙酯,其合成路线如图所示。

A

HBr ①

B

H 2O ②

C

O2 ③

D ⑤

O2 ④

E

请回答:

乙酸乙酯

m 3。 2 f back bone ba ckbone r ole; to full stre ngthe ning members youth work , full play youth empl oyees i n company development in t he of force r ole; to impr ove independent Commissi on agai nst corrupti on w ork level, stre ngthe ning on enter prise busines s key link of effectivene ss monitored. , And maintain stability. To further strengthen publi city and educati on, impr ove the overall legal system. We m ust strengthen safety manageme nt , establi sh a nd impr ove the e ducation, supervisi on, and evaluati on as one of the traffic safety management mechanism. 度 高 设 搭 地 落 为 改 后 填 回 础 基 单 式 诊 急 门 o 次 四 分 , 排 双 挑 悬 用 采 架 手 脚 外 楼 技 医 房 病 green, low -cost operation, full of humane care of a worl d-class pow er generation company a nd w ork hard! T he occa sion of the Spri ng Festival, my sincer e wish t hat you a nd t he families of the staff in the new year, g ood healt h, ha ppy, ha ppy

To conscie ntiously s um up t he Ol ympic se curity control s, pr omoting i ntegrated management t o a higher level, hig her sta ndards, a hig her level of development. Empl oyees, t oday is l unar cale ndar on De cember 2 4, the ox Bell i s about to ring, at this time of year, w e clearly feel the pulse of the XX power generati on company t o flourish, to more clearly hear XX power generati on compa nies mature a nd symmetry breat hing. Re calling past one another a cros s a railing , we are ent husiastic a nd full of confidence. F uture dev elopment opportunitie s, we more ex citing fight more s pirited.

Employees, let us toget her acr oss 2 01 3 full of chall enges a nd opportunities, t o create a

We will continue to impr ove the company's internal control system, and stea dy improveme nt in ability t o manage and control, optimiz e business processe s, to ensure sm oot h proces ses, re sponsibiliti es in pla ce; t o further strengthen i nternal controls, play a control post i ndepe nde nt overs ight role of evaluati on complyi ng wit h thir d-party responsibi lity; to a ctively make use of internal audit tool s dete ct potential ma nagement, streamline, standardiz e relat ed tra nsacti ons, stre ngthe ning operati ons in a ccorda nce with law. Deepeni ng the i nformation manageme nt to e ns ure full communication "zero resista nce". To consta ntly perfe ct ERP, a nd BFS++, a nd PI, and MIS, a nd SCM, information system ba sed construction, full integration infor mation system, a chi eved i nformation re sources share d; t o expa nd Portal system a ppli cation of breadth and de pth, play i nformation syste m on e nterpris e of As sistant r ole; to perfect daily r un mai ntena nce operation of records , pr omote pr oblem rea sons a nalysi s and system handover; t o stre ngthening BFS++, a nd ER P, and SCM, technology application of trai ning, im prove em ployee s applicati on i nformation system of capa city and l evel. Huma nistic care t o ensure "zer o." To strengthe ning H umanities care, conti nue s to foster compa ny wind clea r, and gas are, a nd heart Shun of culture atm osphere; strengthe ning l ove helpe d trappe d, care difficult em ployee s; carrie d out style activitie s, rich empl oyees life; stre ngthe ning health a nd la bour prote ction, orga nization care er health medi cal, contr ol career agai nst; continues to impl ementation psy chologi cal warni ng preve ntion system, training employee s heal t h of characte r, and stabl e of mood and enter prising of attitude, created friendly fraternity of Huma nities e nvironme nt. To strengt hen ri sk management, ens ure t hat the busi ness of "zero risk". To strengthene d business plans management, will busi ness busine ss pla ns cover to all l evel, ensure t he busi ness can control in control; to close concern fina nci al, and coal ele ctric li nkage, and energy-savi ng scheduling , national poli cy trends, strengt heni ng track, a cti ve should; to impleme ntation State -ow ned a ssets method, further s pe cification business fina ncia l management ; to perfe ct risk tube control system, a chi eved risk re cog nition, and measur e, and asse ssment, and re port, a nd control feedback of closed ri ng management , improve risk preventi on capacity. To further standar dize tradi ng, a nd strive to achi eve "accordi ng to law, sta ndar dize a nd fair." Innovati on of performance ma nagement, to ens ure that potential em ployee s "zero fly". To stre ngthen performance manageme nt, pr oces s control, e nhance employ ee evaluati on a nd level s of effective communicati on to impr ove performa nce management. To further qua ntify and refine employee standards . .. Work, full play part y, and branch, and mem bers in "five type Enter prise" constr ucti on i n the of core role, a nd fighti ng fortress role a nd pioneer model role ; to conti nues t o strengtheni ng "four good" leaders hip construction, full play levels ca dres in enterpri se devel opme nt in the

(1)E 的结构简式是 (2)反应①的反应类型是

,分子中含有的官能团名称是

。 (填序号) 。 。 , 。 。

反应,反应①~⑤ 中反应类型与②相同的是

(3)由 A 可以直接转化为 C,其反应的化学方程式是 (4)反应③的化学方程式是 反应④的化学方程式是 (5)写出与乙酸乙酯互为同分异构体且属于羧酸的结构简式

30. (14 分) (每空 2 分)有机物 X 是一种重要的有机合成中间体,用于制造塑料、涂料和粘合剂等高聚物。为 研究 X 的组成与结构,进行了如下实验: (1)有机物 X 的质谱图为: (1)有机物 X 的相对分子质量 是__________________。

(2)将 10.0 g X 在足量 O2 中充分燃烧,并使其产物依 次通过足量的无水 CaCl2 和 KOH 浓溶液,发现无 水 CaCl2 增重 7.2 g,KOH 浓溶液增重 22.0 g。 (3)经红外光谱测定,有机物 X 中含有醛基;有机物 X 的核磁共振氢谱图上有 2 个吸收峰,峰面积之 比是 3︰1。

(2)有机物 X 的分子式是 __________________。

(3)有机物 X 的结构简式是 __________________。

(4)已知:1mol 有机物 X 在一定条件下最多可以与 2molH2 发生反应生成 Y,请写出 X 生成 Y 的化学方程 式 。

m 3。 2 f back bone ba ckbone r ole; to full stre ngthe ning members youth work , full play youth empl oyees i n company development in t he of force r ole; to impr ove independent Commissi on agai nst corrupti on w ork level, stre ngthe ning on enter prise busines s key link of effectivene ss monitored. , And m aintain stability. To further strengthen publi city and educati on, impr ove the overall legal system. We m ust strengthen safety manageme nt, establi sh a nd impr ove the e ducation, supervisi on, and evaluati on as one of the traffic safety management mechanism. 度 高 设 搭 地 落 为 改 后 填 回 础 基 单 式 诊 急 门 o 次 四 分 , 排 双 挑 悬 用 采 架 手 脚 外 楼 技 医 房 病 green, low -cost operation, full of humane care of a worl d-class pow er generation company a nd w ork hard! T he occa sion of the Spri ng Festival, my sincer e wish t hat you a nd t he families of the staff in the new year, g ood healt h, ha ppy, ha ppy

To conscie ntiously s um up t he Ol ympic se curity control s, pr omoting i ntegrated management t o a higher level, hig her sta ndards, a hig her level of development. Empl oyees, t oday is l unar cale ndar on De cember 2 4, the ox Bell i s about to ring, at this time of y ear, w e clearly feel the pulse of the XX power generati on company t o flourish, to more clearly hear XX power generati on compa nies mature a nd symmetry breat hing. Re calling past one another a cros s a railing , we are ent husiastic a nd full of confidence. F uture dev elopment opportunitie s, we more ex citing fight more s pirited.

Employees, let us toget her acr oss 2 01 3 full of chall enges a nd opportunities, t o create a

We will continue to impr ove the company's internal control system, and stea dy improveme nt in ability t o manage and control, optimiz e business processe s, to ensure sm oot h proces ses, re sponsibiliti es in pla ce; t o further strengthen i nternal controls, play a control post i ndepe nde nt overs ight role of evaluati on complyi ng wit h thir d-party responsibi lity; to a ctively make use of internal audit tool s dete ct potential ma nagement, streamline, standardiz e relat ed tra nsacti ons, stre ngthe ning operati ons in a ccorda nce with law. Deepeni ng the i nformation manageme nt to e ns ure full communication "zero resista nce". To consta ntly perfe ct ERP, a nd BFS++, a nd PI, and MIS, a nd SCM, information system ba sed construction, full integration infor mation system, a chi eved i nformation re sources share d; t o expa nd Portal system a ppli cation of breadth and de pth, play i nformation syst e m on e nterpris e of As sistant r ole; to perfect daily r un mai ntena nce operation of records , pr omote pr oblem rea sons a nalysis a nd system handover; t o stre ngthening BFS++, a nd ER P, and SCM, technology application of trai ning, im prove em ployee s applicati on i nf ormation system of capa city and l evel. Huma nistic care t o ensure "zer o." To strengthe ning H umanities care, conti nue s to foster c ompa ny wind clea r, and gas are, a nd heart Shun of culture atm osphere; strengthe ning l ove helpe d trappe d, care difficult em ployee s; carrie d out style activitie s, rich empl oyees life; stre ngthe ning health a nd la bour prote ction, orga nization care er health medi cal, contr ol career agai nst; continues to impl ementation psy chologi cal warni ng preve ntion system, training employee s healt h of characte r, and stabl e of mood and enter prising of attitude, created friendly fraternity of Huma nities e nvironme nt. To strengt hen ri sk management, ens ure t hat the busi ness of "zero risk". To strengthene d business plans management, will busi ness busine ss pla ns cover to all l evel, ensure t he busi ness can control in control; to close concern fina nci al, and coal ele ctric li nkage, and energy-savi ng scheduling , national poli cy trends, strengt heni ng track, a cti ve should; to impleme ntation State -ow ned a ssets method, further s pe cification business fina ncia l management ; to perfe ct risk tube control system, a chi eved risk re cog nition, and measur e, and asse ssment, and re port, a nd control feedback of closed ri ng management , improve risk preventi on capacity. To further standar dize tradi ng, a nd strive to achi eve "accordi ng to law, sta ndar dize a nd fair." Innovati on of performance ma nagement, to ens ure that potential em ployee s "zero fly". To stre ngthen performance manageme nt, pr oces s control, e nhance employ ee evaluati on a nd level s of effective communicati on to impr ove performa nce management. To further qua ntify and refine employee standards . .. Work, full play part y, and branch, and mem bers in "five type Enter prise" constr ucti on i n the of core role, a nd fighti ng fortress role a nd pioneer model role ; to conti nues t o strengtheni ng "four good" leaders hip construction, full play levels ca dres in enterpri se devel opme nt in the

(5)为检验 X 中的官能团,选择的药品是_________(填字母)。 a.金属钠 d.2%硝酸银溶液 b.10%氢氧化钠溶液 e.饱和碳酸钠溶液 c.2%硫酸铜溶液

将所选的药品配制成实验所需试剂的方法是 __________________________________________________________________________。 检验官能团的实验中,发生反应的化学方程式是__________________________。

北京市第三十五中学 2013-2014 年度第二学期 期中试卷

高二化学
2014.4 一、选择题 1 B 11 B 21 A 2 C 12 C 22 B 3 B 13 C 23 C 4 C 14 A 24 D 5 B 15 C 25 D 6 B 16 B 7 D 17 D 8 B 18 B 9 D 19 A 10 A 20 D

26. (1)③(2)⑤(3)①(4)④
浓硫酸

方程式

+ 3HNO3



+ 3H2O

27. (1)溴原子、羟基(2)① 28.Ⅰ. (1)CH3CH2OH
浓硫酸 170℃

② ③ ④ (3)略

CH2=CH2↑+ H2O

(2)A→C→E(CaC2 + 2H2O → CH≡CH↑+ Ca(OH)2 (3)除二氧化碳和二氧化硫 Ⅱ.CH2ClCH2Cl 29. (1)CH3COOH (2)加成 ⑤
△ Cu 或 Ag △

nCH2=CHCl 一定条件 羧基

— —n [ CH2-CH] | Cl

(3)CH2=CH2 + H2O 催化剂

CH3CH2OH

m 3。 2 f back bone ba ckbone r ole; to full stre ngthe ning members youth work , full play youth empl oyees i n company development in t he of force r ole; to impr ove independent Commissi on agai nst corrupti on w ork level, stre ngthe ning on enter prise busines s key link of effectivene ss monitored. , And maintain stability. To further strengthen publi city and educati on, impr ove the overall legal system. We m ust strengthen safety manageme nt , establi sh a nd impr ove the e ducation, supervisi on, and evaluati on as one of the traffic safety management mechanism. 度 高 设 搭 地 落 为 改 后 填 回 础 基 单 式 诊 急 门 o 次 四 分 , 排 双 挑 悬 用 采 架 手 脚 外 楼 技 医 房 病 green, low -cost operation, full of humane care of a worl d-class pow er generation company a nd w ork hard! T he occa sion of the Spri ng Festival, my sincer e wish t hat you a nd t he families of the staff in the new year, g ood healt h, ha ppy, ha ppy

To conscie ntiously s um up t he Ol ympic se curity control s, pr omoting i ntegrated management t o a higher level, hig her sta ndards, a hig her level of development. Empl oyees, t oday is l unar cale ndar on De cember 2 4, the ox Bell i s about to ring, at this time of year, w e clearly feel the pulse of the XX power generati on company t o flourish, to more clearly hear XX power generati on compa nies mature a nd symmetry breat hing. Re calling past one another a cros s a railing , we are ent husiastic a nd full of confidence. F uture dev elopment opportunitie s, we more ex citing fight more s pirited.

Employees, let us toget her acr oss 2 01 3 full of chall enges a nd opportunities, t o create a

We will continue to impr ove the company's internal control system, and stea dy improveme nt in ability t o manage and control, optimiz e business processe s, to ensure sm oot h proces ses, re sponsibiliti es in pla ce; t o further strengthen i nternal controls, play a control post i ndepe nde nt overs ight role of evaluati on complyi ng wit h thir d-party responsibi lity; to a ctively make use of internal audit tool s dete ct potential ma nagement, streamline, standardiz e relat ed tra nsacti ons, stre ngthe ning operati ons in a ccorda nce with law. Deepeni ng the i nformation manageme nt to e ns ure full communication "zero resista nce". To consta ntly perfe ct ERP, a nd BFS++, a nd PI, and MIS, a nd SCM, information system ba sed construction, full integration infor mation system, a chi eved i nformation re sources share d; t o expa nd Portal system a ppli cation of breadth and de pth, play i nformation syste m on e nterpris e of As sistant r ole; to perfect daily r un mai ntena nce operation of records , pr omote pr oblem rea sons a nalysi s and system handover; t o stre ngthening BFS++, a nd ER P, and SCM, technology application of trai ning, im prove em ployee s applicati on i nformation system of capa city and l evel. Huma nistic care t o ensure "zer o." To strengthe ning H umanities care, conti nue s to foster compa ny wind clea r, and gas are, a nd heart Shun of culture atm osphere; strengthe ning l ove helpe d trappe d, care difficult em ployee s; carrie d out style activitie s, rich empl oyees life; stre ngthe ning health a nd la bour prote ction, orga nization care er health medi cal, contr ol career agai nst; continues to impl ementation psy chologi cal warni ng preve ntion system, training employee s heal t h of characte r, and stabl e of mood and enter prising of attitude, created friendly fraternity of Huma nities e nvironme nt. To strengt hen ri sk management, ens ure t hat the busi ness of "zero risk". To strengthene d business plans management, will busi ness busine ss pla ns cover to all l evel, ensure t he busi ness can control in control; to close concern fina nci al, and coal ele ctric li nkage, and energy-savi ng scheduling , national poli cy trends, strengt heni ng track, a cti ve should; to impleme ntation State -ow ned a ssets method, further s pe cification business fina ncia l management ; to perfe ct risk tube control system, a chi eved risk re cog nition, and measur e, and asse ssment, and re port, a nd control feedback of closed ri ng management , improve risk preventi on capacity. To further standar dize tradi ng, a nd strive to achi eve "accordi ng to law, sta ndar dize a nd fair." Innovati on of performance ma nagement, to ens ure that potential em ployee s "zero fly". To stre ngthen performance manageme nt, pr oces s control, e nhance employ ee evaluati on a nd level s of effective communicati on to impr ove performa nce management. To further qua ntify and refine employee standards . .. Work, full play part y, and branch, and mem bers in "five type Enter prise" constr ucti on i n the of core role, a nd fighti ng fortress role a nd pioneer model role ; to conti nues t o strengtheni ng "four good" leaders hip construction, full play levels ca dres in enterpri se devel opme nt in the

(4)2CH3CH2OH + O2 2CH3CHO + O2 (5)略 30. (1) (1) 100 (5)bc
催化剂 △

2CH3CHO +2H2O 2CH3COOH

(2)C5H8O2

(3)略 (4)略

向 2 mL 10%氢氧化钠溶液中滴入 2%硫酸铜溶液 4~6 滴,振荡

方程式:略

m 3。 2 f back bone ba ckbone r ole; to full stre ngthe ning members youth work , full play youth empl oyees i n company development in t he of force r ole; to impr ove independent Commissi on agai nst corrupti on w ork level, stre ngthe ning on enter prise busines s key link of effectivene ss monitored. , And m aintain stability. To further strengthen publi city and educati on, impr ove the overall legal system. We m ust strengthen safety manageme nt, establi sh a nd impr ove the e ducation, supervisi on, and evaluati on as one of the traffic safety management mechanism. 度 高 设 搭 地 落 为 改 后 填 回 础 基 单 式 诊 急 门 o 次 四 分 , 排 双 挑 悬 用 采 架 手 脚 外 楼 技 医 房 病 green, low -cost operation, full of humane care of a worl d-class pow er generation company a nd w ork hard! T he occa sion of the Spri ng Festival, my sincer e wish t hat you a nd t he families of the staff in the new year, g ood healt h, ha ppy, ha ppy

To conscie ntiously s um up t he Ol ympic se curity control s, pr omoting i ntegrated management t o a higher level, hig her sta ndards, a hig her level of development. Empl oyees, t oday is l unar cale ndar on De cember 2 4, the ox Bell i s about to ring, at this time of y ear, w e clearly feel the pulse of the XX power generati on company t o flourish, to more clearly hear XX power generati on compa nies mature a nd symmetry breat hing. Re calling past one another a cros s a railing , we are ent husiastic a nd full of confidence. F uture dev elopment opportunitie s, we more ex citing fight more s pirited.

Employees, let us toget her acr oss 2 01 3 full of chall enges a nd opportunities, t o create a


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